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Material Safety Data Sheet Part A
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Material Safety Data Sheet
Date Prepared 08/01/07
Section 1: Product and Company Identification
Product Name:
Polyaspartic Clear Coat-Part A
Sold By:
Slide-Lok 11803 N Saguaro Blvd, Fountain Hills AZ 85268 (480)222-9720
FOR CHEMICAL EMERGENCY
Spill, leak, fire, exposure, or accident, call 24 hours 800-835-1759
Fax Phone:
480-222-9711
Section 2: Composition/Information on Ingredients
Hazardous Components
CAS#
ACGIH TLV
OSHA PEL
1,6 Hexamethylene Diisocyanate Benzene, 1-chloro-4-(Triflouromethyl)
822-06-0 98-56-6
Not Determined
Not Determined
2
Section 3: Hazards Identification
Emergency Overview:
Routes of Entry:
Route
Entry Risk
Inhalation
Possible
Ingestion
Possible
Skin Contact
Possible
Eye Contact
Possible
Potential Health Effects:
Inhalation
May cause nausea and respiratory tract irritation. May cause respiratory sensitization in susceptible individuals.
Ingestion
No significant signs or symptoms of any adverse health hazards.
Skin Contact
Product is a slight skin irritant. May Cause swelling and redness.
Eye Contact
Mild eye irritant. Vapors slightly uncomfortable. Splashes irritating and painful.
Acute Health Hazards:
No information is available on the acute health hazards of this product. Based upon data from testing of similar products, no significant effects are expected.
Chronic Health Hazards:
If misted or at high concentrations, may cause pallor, nausea, anesthetic or narcotic effects.
Medical Conditions Generally Aggravated by Exposure: Carcinogenicity:
Skin and eye sensitization. Depending on individual skin sensitivity, chronic or prolonged exposure may result in irritation, blistering, burning and peeling of skin layers. OSHO: No Data ACGIH: No Data NTP: No Data IARC: No Data
Section 4: First Aid Measures
Eye Contact:
Immediately flush with plenty of water for at least 15 minutes. If redness, itching, or a burning sensation develops, seek medical attention.
Skin Contact:
Remove from skin immediately. Rinse with clean water for 20-30 minutes. Use soapy water if needed. If redness, itching, or a burning sensation develops, seek medical attention.
Ingestion:
Do NOT induce vomiting! Dilute with water and seek medical attention immediately.
Inhalation:
Move victim to fresh air immediately. Give oxygen and seek medical attention.
Section 5: Fire-Fighting Measures
Flammable Limits:
Not determined
Flash Point, (Method Used): Autoignition Tempature:
Approximately 42.8 ̊C (109 ̊F) Tag CC Approximately > 500 ̊C
NFPA Hazard Rating:
Health:
2
Hazard Scale
Protective Equipment
0=LEAST 1=SLIGHT 2=MODERATE 3=HIGH 4=EXTREME
A=SAFETY GLASSES B=SAFETY GLASSES, GLOVES C=SAFETY GLASSES, GLOVES AND APRON
Flammability:
2
Reactivity:
1
Other:
HMIS Hazard Rating:
Health:
2
Flammability:
2
Reactivity:
1
Protection:
B
Extinguishing Media:
Foam/Carbon dioxide/Dry Chemical/Water fog
Special Fire Fighting Procedures:
Remove all ignition sources. Wear self-contained breathing apparatus and complete personal protective equipment when entering confined areas where potential for exposure to vapors or products exist.
Unusual Fire and Explosion Hazards:
Closed containers may rupture due to build-up of pressure when exposed to extreme heat.
Section 6: Accidental Release Measures
Accidental Release Measures:
Avoid contact with material. Persons not wearing appropriate protective equipment should be excluded until spill is cleaned up. Stop spill at source, pump liquid to salvage container. Remaining liquid may be taken up on clay, diatomaceous earth, or other absorbent. Treat with Decontamination Solutions: Nonionic surfactant Union Carbide's Tergitol TMN-10 (20%) and water (80%); concentrated ammonia (3-8%), detergent (2%) and water (90-95%).
Section 7: Handling and Storage
Handling & Storage Precautions:
Prevent all skin and eye contact. Avoid breathing vapors. Re-seal partially used containers. Wash with soap and water before eating or drinking. Protect from moisture contamination. Exothermic generation of carbon dioxide may cause dangerous pressure. Keep away from all ignitable sources as well as extreme heat. Do not expose to excessive moisture.
Section 8: Exposure Control/Personal Protection
Ventilation:
Adequate ventilation required. Local exhaust may be required in some areas. Special exhausting generally not required. Mechanical exhaust usually adequate.
Respiratory Protection:
Respiratory masks should be worn at all times when adequate ventilation does not exist. A NIOSH/MSHA respirator is acceptable.
Eye Protection:
Chemical tight goggles; full face shield if splashing is possible.
Skin Protection:
Avoid all skin contact.
Other Protective Clothing or Equipment:
Use impervious gloves, neoprene or rubber.
Work/Hygenic Practices:
Good air flow in working area. Eyewash station and safety shower should be available. Gloves and respiratory equipment should be worn at all times.
Section 9: Physical and Chemical Properties
Appearance:
Clear/ Colorless
Odor:
Negligible
Physical State:
Liquid
ph As Supplied:
Not applicable
Boiling Point:
Begins at > 139 ̊C (282° F)
Melting Point:
-36 ̊C (-33 ̊F)
Pour Point:
Approx -51C (59.8F)
Vapor Pressure (mmHg):
=7.5-5 mmHG @ 77° Fahrenheit for MDI
Specific Gravity (Water=1):
1.199 @ 20°C (68 ̊ F)
Volatile Organic Compounds (VOC):
With water: None Without water: None
Solubility in Water:
Not soluble (reacts to liberate Co2 gas)
Percent Volatile: Bulk Density: Molecular Weight
By weight: Negligible 9.98 Lb./ Gal 500 Approximate Value, for the polyisocyanate
Section 10: Stability and Reactivity
Stability:
Stable
Conditions to Avoid (Stability):
Avoid excessive heat, open flame, sparks and strong oxidizing agents. Protect from atmospheric moisture. Replace outage with inert dry nitrogen.
Incompatibility (Materials to Avoid):
Avoid water, acid, base (alkalis, ammonia), alcohols, metal compounds.
Hazardous Decomposition or Byproducts:
Isocyanate vapors or mist, carbon dioxide, carbon monoxide, nitrogen oxides.
Hazardous Polymerization:
May Occur
Conditions to Avoid (Polymerization):
Avoid incompatible reactants, especially strong bases, water or temperatures over 160° Centigrade.
Section 11: Toxicological Information
Toxicological Information (Acute Toxicity):
ORAL LD50: Estimated to be greater than 10000 MG/KG (rats) DERMAL LD50: Estimated to be greater than 5000 MG/KG (rabbits) INHALATION LC50: Lower Respiratory (Pulmonary) Irritant. LC 50 Value Range from 137-1150 MG/M3 were obtained in rats exposed to aerosols. (4H EXP.) Severe irritant capable of inducing corneal injury (rabbit) Maximum primary eye irritant score: 54.6/110 for 24 hour skin effects: Moderate and Dermal. Primary dermal irritation score: 3.4/8.0 (rabbit). Pulmonary and dermal sensitizer in animals and humans.
Section 12: Ecological Information
Ecological Information:
No Data
Section 13: Disposal Considerations
Waste Disposal Method:
Dispose of according to current local, state, and federal regulations.
RCRA Hazard Class:
Non-Regulated
Section 14: Transport Information
U.S. Department of Transportation
Proper Shipping Name:
Polyisocyanate
Hazard lass: ID Number: Packing Group:
Non-regulated in 55 gallon drums, NOI NA 3082 III
Water Transportation
Hazard Class:
Non-regulated, NOI
Air Transportation
Hazard Class:
Non-regulated, NOI
Section 15: Regulatory Information
U.S. Federal Regulations
TSCA Toxic Substance Control Act: CERCLA (Comprehensive Response Compensation and Liability Act: SARA Title III (Superfund Amendments and Reauthorization Act: 311/312 Hazard Categories:
Listed on the TSCA Inventory (40 CFR302): None Immediate health hazard; Delayed health hazard; Reactive hazard; Fire hazard.
313 Reportable Ingredients:
None
RCRA Status:
When discarded in its purchased form, this product meets the criteria of ignitability, and should be managed as a hazardous waste. (EPA Hazardous Waste Number D001) (40 CFR 261.20-24)
State Regulations:
Homopolymer of HDI 28182-81-2, 83%, PA, NJ. Aromatic 100 (Solvent NAPHTHA) (AR100) 64742-95-6, 4.6%, PA, NJ. N-Butyl Acetate (BA) 123-86-4, 4.6%, PA, MA, NJ. Acetate Ester 90438-79-2, 7.8%, PA, NJ. California Proposition 65 To the best of our knowledge, this product contains no levels of listed substances which the state of California has found to cause cancer, birth defects or other reproductive effects.
Section 16: Other Information
Disclaimer:
This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.
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